RESUMO
The synthesis of Bio-MOF using aspartic acid as an organic linker and water as a solvent was performed to create an environmentally friendly material. The chemical composition, structure, and morphology of the synthesized zirconium Bio-MOF (MIP-202) was evaluated using X-ray diffraction (XRD), energy dispersive X-ray (EDX) spectroscopy, transmission electron microscopy (TEM), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The synthesized Bio-MOF was used as an adsorbent for trimethoprim antibiotic as pollutants from an aqueous solution under various operating parameters. The increase in the initial trimethoprim concentration from 2.5 mg/L to 20 mg/L decreased the decontamination efficiency from 77.6% to 35.9% at a solution pH of 7 with 0.5 g/L adsorbent dose after 60 min reaction time. The rise of adsorbent dose from 0.1 g/L to 1.5 g/L increased the removal efficiency from 47.7% to 87.6%. The maximum trimethoprim removal efficiency of 95% was attained at a solution pH of 11. Langmuir and pseudo-second order models described the adsorption process of trimethoprim antibiotic onto zirconium Bio-MOF and the chemo-physical nature of trimethoprim adsorption onto the synthesized zirconium Bio-MOF. Accordingly, it was evident that the prepared zirconium Bio-MOF (MIP-202) is an ecofriendly and efficient adsorbent for antibiotic decontamination from polluted water.
RESUMO
Organophosphate-based pesticides, such as diazinon, are among the most toxic organic contaminants to human and environment. Effective removal of diazinon from contaminated water sources is critical. Zirconium Metal-organic frameworks (Zr-MOFs) are promising candidates for the removal of organic contaminants from wastewater. Herein, we report the adequacy of a bio based Zr-MOF named MIP-202 for the removal of diazinon from water. On the other hand, the use of these materials in powder form is not workable, the development of scalable and economical processes and integrative of these materials onto beads is paramount for industrial processes. Hence, it was reported a scalable, bio aqueous solution-based preparation strategy for Bio Zr-MOF beads production. The composite material exposed identical reactivity under the same ambient parameters compared to powdered material in an aqueous solution. These results signify a critical procedure to an integrated strategy for organophosphates removal using bio-based MOFs, which demonstrates high potential for manufacturing applications such as continued removal of organophosphates from wastewater supplies.
RESUMO
This reported work aims to fabricate an eco-friendly Zr bio-based MOF and assessment its adsorption efficiency towards the cationic and anionic dye pollutants including methylene blue (MB) and direct red 81 (DR-81), respectively. Also, its adsorption tendency for the highly toxic heavy metal of hexavalent chromium (Cr(VI)) was compared with dyes. The adsorption performance of bio-MOF showed that the maximum monolayer adsorption capacities were recorded as 79.799 mg/g for MB, 36.071 mg/g for DR-81, and 19.012 mg/g for Cr(VI). Meanwhile, the optimum dosage of as-synthesized MIP-202 bio-MOF was 0.5, 1, and 2 g L-1 for MB, DR-81, and Cr(VI), respectively. Thermodynamic analysis demonstrated the spontaneous, thermodynamically, and endothermic nature of the decontamination processes onto the fabricated Zr bio-based MOF. The adsorption data were fitted by Langmuir isotherm model compared with Freundlich and Temkin models for all studied water pollutants. Pseudo-second-order kinetic model was a fit model for description of the adsorption kinetics of the different cationic and anionic pollutants onto Zr bio-based MOF. These outcomes indicated that Zr bio-based MOF has potential application for adsorption of different types of industrial water pollutants including cationic and anionic dyes and heavy metals.
